Carbocation Chemistry碳阳离子化学

出版时间：2004-10  出版社：吉林长白山  作者：Prakash, G. K. Surya; Olah, George A.; Prakash, G. K. Surya  页数：393  

内容概要

“an excellent book， which should be in every good chemistry department library。” 　　“The field continues to be of major significance and the book is a valuable volume for those who follow such charged species in catalytic reactions。” 　　a fascinating collection of review articles on this topic。　　A detailed understanding of reactive intermediates is at the heart of chemical transformations，and thus of modern organic synthetic chemistry。 Carbocations are electron deficient species that are the most important intermediates in organic chemistry。This comprehensive review gives practical information on the synthesis， mechanisms，and spectral studies related to carbocation chemistry。　　* A detailed reference for all aspects of charbocation chemistry。　　* With numerous classical examples of studies of carbocations to serve as illustrative principles in organic and physical organic chemistry。　　* Provides insight into future developments in the field and practical applications。

书籍目录

1 Historical perspective 2 100 years of carbocations and their significance in chemistry  3 Zwitterionic“neutral” and“anionic” carbocation analogs 4 Recent studies of long-lived carbocations and carbodications 5 Antiaromaticity effects in cyclopentadienyl carbocations and free radicals 6 Long-lived carbocations in cold Siberia 7 Polyfluorinated carbocations 8 Carbocations, fast rearrangement reactions, and the isotopic perturbation method 9 Stable ion chemistry of polycyclic aromatic hydrocarbons （PAHs）；modeling electrophiles from carcinogens 10 Chromium tricarbonyl-coordinated carbocations11 Carbocations in gold chemistry12 Proton exchange between strong acids and alkanes 13 Electrophilicity scales for carbocations 14 Organic synthesis in superacids